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Enhanced C2-CN sub-mechanism: Impact on NO/N2O and soot precursor yields during C2H2/HCN oxidation

The combustion of hydrocarbon-ammonia fuels poses challenges related to the formation of soot and nitrogen oxides (NOx) emissions. Various kinetic mechanisms have been developed to describe the pathways of soot and NOx formation, but limited …

On the roles of humidification and radiation during the ignition of ammonia-hydrogen-air mixtures

High-pressure kinetic interactions between CO and H2 during syngas catalytic combustion on PdO

The catalytic combustion of H2/CO/O2/N2 mixtures over PdO was investigated at pressures 3 to 10 bar, H2:CO volumetric ratios 1:5 to 3:1, and global equivalence ratios φ = 0.13 and 0.23. The catalyst surface temperatures were controlled to 540-690 K, …

Fuel-rich hetero-/homogeneous combustion of C3H8/O2/N2 mixtures over rhodium

The catalytic (heterogeneous) and gas-phase (homogeneous) combustion of C3H8/O2/N2 mixtures over rhodium was investigated experimentally and numerically at 5 bar and at fuel rich equivalence ratios φ = 2.0 3.5 relevant to propane Catalytic Partial …

Combustion of biomass pyrolysis gas: Roles of radiation reabsorption and water content

Biomass energy has drawn increased attention owing to its zero carbon emissions and large reserves. Pyrolysis instead of direct combustion is an efficient and clean way for biomass energy conversion. As a strong radiative species, H2O greatly affects …

Impact of ammonia addition on soot and NO/N2O formation in methane/air co-flow diffusion flames

Effects of simultaneous CO2 addition to the fuel and oxidizer streams on soot formation in co-flow diffusion ethylene flame

Soot formation in a co-flow diffusion ethylene flame with the addition of CO2 to the fuel (the CO2-F), oxidizer (the CO2-O), and fuel/oxidizer (the CO2-F/O) streams was numerically and experimentally investigated in this study. The effects of …

Experimental detection of two-dimensional temperature distribution in Rocket-Based Combined Cycle combustion chamber using multispectral imaging processing

The extremely harsh environment and highly unsteady and transient nature during supersonic combustion bring great challenges for quantitative diagnostics. In the present work, for the first time, we report measurements of two-dimensional …

Kinetic modeling of total oxidation of propane over rhodium

The heat release rates of fuel-lean propane/air mixtures over a rhodium wire catalyst were measured with microcalorimetry experiments and simulated with a 2D reactive code. Based on these studies, global reaction parameters of the total oxidation of …

Effects of radiation reabsorption on laminar NH3/H2/air flames

Ammonia combustion, owing to its zero greenhouse gas CO2 emission, is attracting attention for energy utilization. However, the thermal radiation of NH3 has not been reported and involved in the numerical simulations of ammonia flames, which may …